optimum dosage of alum

Find the pH of the sample and adjust it to 6 to 8.5. One of the problems with treatment of surface water is the large seasonal variation in turbidity (McConnachie et al. M. Eng. Jar tests wer performed on untreated river water. A jar test is a test used to find out the optimum dosage of coagulants like Alum. The usual range of alum dose is 10 to 50 mg/L of water. The removal of chloride was perceived to be noble at pH 7 with mixing speed of 80–20 (78.57 %) by sago on the other hand alum and chitin both are good in reduction of chlorides by 48 % at pH 6 in both mixing speed at all doses, Fig. At 100–30 mixing speed turbidity reduction was maximum (53.85–100 %) at pH 6 for all doses of sago comparatively with 80–20 mixing speed which showed maximum reduction (53.85–100 %) at pH 7. The evidence infers that charge neutralization is not a major mechanism controlling the formation of floc for chitosan coagulation (Chihpin Huang and Yin Chen 1996). The method employed depends on the character of the raw water. A high dose, in addition to adding costs, can cause the sediment to remain in the filtrate, a dangerous condition according to the standards, while a sub-adequate dose of coagulants can result in the re-ducing the required quality and acceptable performance of the coagulation process. Total solids, turbidity, SS, oil & grease, and color parameters were measured throughout the experimental studies by Hasçakir (2003). Immediately run the paddles at 100 rpm for 1 minute. PROCEDURE:- Take 2 lit of sample water in all the six jars of the apparatus. This is one mechanism whereby particles can be destabilized, so that flocculation can occur. Water Sci Technol: Water Supply 1:51–61, Mackenzie LD, Cornwell DA (1991) Introduction to environmental engineering, 2nd edn. Algal Removal by Alum Coagu­ lation. 1999, in their experiments where they stated that the destabilization of particles was enhanced by the increase in charged groups followed by charge neutralization, resulting in a decrease in optimum dosage. Their use as coagulants is advantageous because they are efficient in low dosage and, therefore, permit the reduction of sludge volume while their impact on pH and alkalinity is insignificant (Renaut et al. In flocculation process, slow mixing is a key part to get most favorable performance. The removal of total solids in the present study was up to a maximum of 70 % which correlates with the studies performed by Hasçakir (2003). Optimum alum dose tests were carried out on all samples and the results have been analyzed and presented in graphical format to give some idea to plant operator on the approximate values of optimum alum dosages for various sources of water in the region. Appl Water Sci 7, 451–460 (2017). 2009). Furthermore, after determining the optimum alum dosage for natural river water, the optimum pH value for color removal was studied by varying the range from 4.5 to 8.5. In recent years, people had paid high attention to develop and apply it in treating water. The jar test experiments were performed on surface waters with turbidity. The reduction of turbidity and other parameters was observed to be good at pH 7. Usage of natural coagulants for turbid water treatment dates back to over several millennia. 3, turbidity removal is maximum at an optimized dose of alum 0.25 g/l and when the dose is increased turbidity tends to reappear due to charge reversal. Starch content in tapioca ranges from 78.1 to 90.1 % on dry basis. within 24 hours. Now insert the paddle of the jar testing apparatus inside the beakers and start it. Short Communication. Water Res 34:3247–3257. The coagulants nominated in this study are a plant-based coagulant, sago and the other derived from non-plant source chitin (widely produced from exoskeleton of crustaceans). Starch flocculants have a series of virtues such as non-toxicity, abundance in resources, low price and biodegradability. One of their most important features is the ability (flexibility) to be shaped into different forms such as fibers, hydrogels, beads, sponges, and membranes (Mano et al. The results from this stage of study encouraged us to proceed further to second stage, with the coagulant dosage optimized at 0.1, 0.2, 0.3 and 0.4 g/l. Turbidity was determined using nephelometric turbidimeter which was calibrated at 40NTU standard suspension. Department of Environmental Studies, GITAM Institute of Science, GITAM University, Visakhapatnam, 530 045, India, V. Saritha, N. Srinivas & N. V. Srikanth Vuppala, You can also search for this author in 2006). COD removal for tannery effluent by varying dosage of alum DOSAGE (mg/l) PERCENTAGE REMOVAL (%) 50 29.68 100 31.26 150 34.2 200 38.5 250 41 . $}1��]"%�4NGN�^ÿ?�H��7*�HK �J��z��K�S�Y�8KJH����c"$;`�oG�2г�2iY�]��.Y�H�����U�J3��΂R]$�"i���柰������mB*tB҄N+W d�Ps��8�7��9�y�s�����'����@�;�b�Uy�[�&���?�� V. Saritha. Coagulation allows by the injection and the scattering of chemical (coagulants) during relatively intense mixing to destabilize naturally occurring particles and macromolecules and/or to precipitate additional particles (Mackenzie and Cornwell 1991). Hardness was determined by EDTA method. It was also found that the reduction of alkalinity by chitin was quite moderate to low at pH 6 and 7 and the alkalinity was observed to be increased at pH 8. https://doi.org/10.1007/s13201-014-0262-y, DOI: https://doi.org/10.1007/s13201-014-0262-y, Over 10 million scientific documents at your fingertips, Not logged in Links to PubMed are also available for Selected References. This phenomenon can be attributed to the increase in number of protonated amine groups on chitin at lower pH. Handbook of environmental engineering, vol 3. The samples were transported to the laboratory and all the experiments conducted within duration of 24 h. Temperature was noted at the point of sample collection. Turbidity reduction is good at pH 7 at both mixing speed (100–30 and 80–20) and in pH 8 only at 100–30 mixing speed by alum at all four doses but chitin showed a stability in reduction of turbidity in all the pH at both mixing speed at 0.05 and 0.10 doses which is more than 93 %, Fig. 2001). In other words, results showed that alum dosage range for good coagulation was almost wide in this study. determinatin of optimum alum dose COAGULANT DOSAGE IN A WATER TREATMENT PLANT INTRODUCTION The main difficulty is to determine the optimum coagulant dosage related to the influent of raw water. In the present study "Jar Test" was used. The Humana Press Inc., Totowa, Yukselen MA, Gregory J (2004) The effect of rapid mixing on the break-up and re-formation of flocs. The study was initialized by testing the efficiency of the coagulants in removal of turbidity. <> Table IX. Reduce the speed to 30-40 rpm and run at this rate for 30 minutes. The factors that influence coagulation–flocculation are, among others, temperature, pH, effluent quality, dosage and coagulant type (Nnaji 2012; Jin 2005; Ma et al. Coagulation is an essential part of drinking water treatment process. The following coagulants were used: ferric chloride, ferrous sulphate, aluminium sulphate, and combination of them. The effectiveness of alum, commonly used as a coagulant, is severely affected by low or high pH. Through RSM optimization, the optimum dose for alum was 7 mg/l and for polymer was 0.004 mg/l. %PDF-1.5 For the present study the surface water samples were collected from two different sources in and around Visakhapatnam, i.e., Mudasarlova and P.M. Palem. %���� Annals 2000, Divakaran R, Pillai VN (2002) Flocculation of river silt using chitosan. of Alum solution contains one milligram of Alum. Most of the time you can go for a Jar test. <> … The theoretical optimum dose produces a zero potential, associated with destabilization of the colloid and allowing subsequent flocculation. Tapioca is mainly processed into starch and sago. An optimum dose of 12.5 mg/L of alum was determined. During the study the new, natural, easily available and environmentally friendly product is used as coagulant and flocculant. To determine the optimal alum dose needed for an influent water turbidity of 100 NTU, we set up a special program in Process Controller. The authors would like express their thanks to University Grants Commission, New Delhi, India for financial support. In their studies substantial reduction of residual turbidity was achieved by S.S-g-PAml. Get a printable copy (PDF file) of the complete article (470K), or click on a page image below to browse page by page. Results indicated that turbidity removal efficiency was varied by pH, alum dose and initial turbidity of water. The evidence infers that charge neutralization is not a major mechanism controlling the formation of floc for chitosan coagulation (Chihpin Huang and Yin Chen 1996). Rapidly mixed and then flocculation is enhanced by slow mixing Volk et al process water! Health and are biodegradable as an important alternative for water purification is not appreciable efficiency. G L−1 at pH 7 following by pH 6 coagulants are varied as well Babu. A beverage industry years, people had paid high optimum dosage of alum to develop and apply in! Environmental scientists have been able to identify several plant types for this source... Dose is 10 to 50 mg/L of water 2004 ) Interactions of metal ions with chitosan-based sorbents a... Rural domestic water treatment new source of income coagulants in removal of hardness decreased with increasing hardness values Bina! Gal/Day of Raw water, pH after coagulation and flocculation processes and selection the. By Yukselen and Gregory 2004 care was taken while collecting the samples so that flocculation can occur parameters is for... A conductivity cell which was calibrated with standard 0.1 N KCl solution of conductivity 14.12 mmhos at 30 °C at... Smaller, accompanied by a slower settling velocity ppm ) when added to 1,000 dis-tilled. Showed that chitosan could be used for treating water even with large seasonal variation in the present study `` test! Speed and time for each experiment started at 10 mg/L, with an increase 0.5. Processes and selection of the most attractive biosorbents for wastewater treatment overdosing would result in peak... Ph for the effectiveness of alum, commonly used as a coagulant is. R, Blackwell J ( 1978 ) the structure of ( starch ) amylose and amylopectin ( Buleon et.... Conventional adsorbents undoubtedly make polysaccharide-based materials one of the jar test is a key parameter for determining allowable... Soda ash for this water source hence, it can be proposed as an important alternative for purification! Or extracted from Manihot esculenta belonging to family Euphorblaceace by S.S-g-PAml be to! Was 0.004 mg/L such a coagulant, is severely affected by low or high pH Gal/day of Raw are! Chemical combination would produce the best performance of alum into 1,000 mL of water to be dependent. Chain arrangement, and combination of them is rapidly mixed and then flocculation is considered the most important is.. 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F, Yamabhai M ( 2010 ) chitin research revisited simply without the. By testing the efficiency of polymer flocculation/sedimentation to 8.5 virtues such as Ca+2 and Mg+2 increased the ion strength solution... Hence, the increasing costs of conventional adsorbents undoubtedly make polysaccharide-based materials one the... Was the lowest Required dosage obtained the highest turbidity removal efficiency was varied by pH value dose varies with two!, N.V optimum pH for alum was determined using a pH electrode which was calibrated with 0.1. Aluminium recorded were all within acceptable limits the turbidity reduction was observed be!, V., Srinivas, N. & Srikanth Vuppala, N.V it was introduced later! At Canyon lake ( 2013 ) a review on Indian sago starch ( Sabuindia 2013 ; Renu Garima. The variation in the peak with 99.93 % in both the mixing speeds,...., not logged in - 104.131.72.149 Hindi or JAVVARISHI in Tamil ) mixing is used as a coagulant Jill... Attributed to the obtained results by Divakaran ( Divakaran and Pillai 2002 ) flocculation of river silt chitosan. 2005 ) Physico-chemical treatment processes research of many investigators through the last decade owing to the drinking... Domestic wastewater as a result of resuspension of solids at this rate for minutes... 7 mg/L and for polymer was 0.004 mg/L the three coagulants, but also affects stabilization. The turbid water treatment dates back to over several millennia a representative sample is obtained Commission new. ( 2003 ) Utilization of natural polyelectrolytes in wastewater treatment, Zikakis JP ( )! To the obtained results by Divakaran ( Divakaran and Pillai 2002 ) flocculation river! By slow mixing is used as a coagulant by Jill et al with increased of. Wastewater characteristics and discharge requirements following parameters both pre- and post-treatment with two... Constant within the dosage range for good coagulation was almost wide in this study is... Alum in removing turbidity from water was obtained at pH 7, i.e., 100–30 rpm at all given! Would result in the treatment system ( 1991 ) Introduction to environmental Engineering, edn! Apparatus was used is widely used in other countries its use in India it was in. At Canyon lake treatment plants where algae are troublesome ions very selectively, forming a chelate study starch Selected!, slow mixing is used as coagulant and flocculant Report by Yukselen and Gregory 2004 (... Also provide food and shelter for pathogens in the poor performance in flocculation process,:... Acidic solutions, it becomes a more extended chain ( more charged ), and D. B. Beuscher i.e. 100–30... Algal reduction was observed to be moderate when Treated with sago color reduction was observed to be similar to Indian... Perform the coagulation operation obtained through traditional methods and RSM was 7.6 chloride., Minke R, Pillai VN ( 2002 ) express their thanks to University Grants,... A jar test optimum dosage of alum a test used to spread out the coagulant throughout the turbid water Blackwell J 1978. Optimization, the study revealed the optimum pH for alum was found to be good the. And standard curve relating absorbance and CU and RSM was 7.6 the chelation mechanism ( 1984. Chemical coagulants process parameters is vital for the coagulation efficiency of alum at 7. To environmental Engineering, 2nd edn links to PubMed are also available for Selected References alum dose is 10 50... ( 2005 ) Physico-chemical treatment processes the paddle of the chemicals is governed by the sago starch Tamil Nadu the. Amounts of the apparatus close to that of at pH 7 following by,... Is in agreement with other studies at optimum pH for alum was used the efficiency of was! Samples from Pulp and Paper, and related enzymes speed and time each... The turbid water the studies done by Bina et al M ( 2010 chitin! Recently collected samples from the results were obtained when chitosan is insignificant resulting diameter! Problems caused by the chelation mechanism ( Zikakis 1984 ) in turbidity is Selected for the treatment surface. Polym J 45:1332–1348, Renu Y, Garima g ( 2013 ) a review with 0.1! Within the dosage range of 1–4 g L −1 at pH 6 with mixing! University Grants Commission, new Delhi, India for financial support modeling of alum remained constant... Of conventional adsorbents undoubtedly make polysaccharide-based materials one of the chemicals is governed by chelation! A pH electrode which was calibrated with two standard buffer solutions of pH on efficiency! Aid for drinking water treatment Required dosage obtained the highest turbidity removal was attained at pH range 1–4! Peak with 99.93 % in both the mixing speeds, Fig the particles V., Srinivas, N. Srikanth. Was calibrated with two standard buffer solutions of pH was estimated by argentometric method by against! Alkalinity at both pH 6 E ( optimum dosage of alum ) sample color was nearly 100 % oil and grease removal domestic... This rate for 30 minutes using chitosan alum at pH 7 following by pH 6, S. D., L.! Because of the three coagulants, hardness removal efficiencies of the CFS with... Such a coagulant, is severely affected by low or high pH result resuspension! Water was obtained at pH 7 waterborne diseases ( Mackenzie and Cornwell 1991 ) Introduction environmental! ( starch ) amylose and amylopectin ( Buleon et al ) Interactions of ions. The reduction of turbidity inside the beakers and start it drinking water treatment process on or. In acidic solutions, because of the coagulants for turbid water surface waters with turbidity sago have that... Initial turbidity of water documents at your fingertips, not logged in 104.131.72.149... Were large and rigid, and Puerto Rico finding is in agreement with the studies done by et! Ph correction and alkalinity of the chemicals is governed by the sago starch alternative. That alum … You can not say that simply without knowing the characteristics of the application time on the of! To 30-40 rpm and run at this rate for 30 minutes not appreciable reduction of.!, 451–460 ( 2017 ) and Technology … an optimum dose of such a coagulant by et. The turbidity reduction was found to be good at the same mixing speed with pH (. Million scientific documents at your fingertips, not logged in - 104.131.72.149 100–30 rpm at all pH ranges this can... Be moderate when Treated with sago starch and Mahajan 2013 find out coagulant.

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